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328227 Aldrich

(1S)-(−)-Camphanic acid

98%

Synonym: (−)-Camphanic acid, (1S)-3-Oxo-4,7,7-trimethyl-2-oxabicyclo[2.2.1]heptane-1-carboxylic acid

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Properties

Related Categories Asymmetric Synthesis, Carboxylic Acids, Chemical Synthesis, Chiral Building Blocks, Chiral Resolution Reagents,
InChI Key   KPWKPGFLZGMMFX-VHSXEESVSA-N
assay   98%
optical activity   [α]20/D −18°, c = 1 in dioxane
optical purity   ee: 98% (GLC)
mp   201-204 °C(lit.)

Description

Packaging

1, 5 g in glass bottle

Application

(1S)-(-)-Camphanic acid may be used in the preparation of (-)-(1S,4R)-camphanoyl chloride by reacting with thionyl chloride.

General description

(1S)-(-)-Camphanic acid is commonly used as a chiral auxiliary for the separation of racemates.

Price and Availability

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles
Peer-Reviewed Papers
15

References

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