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335274 Aldrich

2,2-Dimethyl-3(2H)-furanone

96%

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Properties

Related Categories Building Blocks, C4 to C7, Chemical Synthesis, Furans, Heterocyclic Building Blocks More...
InChI Key   HVNICCSXGONRCB-UHFFFAOYSA-N
assay   96%
refractive index   n20/D 1.455(lit.)
bp   46-47 °C/18 mmHg(lit.)
density   1.027 g/mL at 25 °C(lit.)
storage temp.   2-8°C

Description

Packaging

1 g in glass bottle

Application

2,2-Dimethyl-3(2H)-furanone was used in the synthesis of epoxides via epoxidation. It was also used in the preparation of racemic methyl nonactate.

General description

2,2-Dimethyl-3(2H)-furanone is an β-oxo enol ether. Conjugate addition of 2,2-dimethyl-3(2H)-furanone to organocuprates has been reported. Photoannelation of alkenes to 2,2-dimethyl-3(2H)-furanone yields cyclohexenone.

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Safety & Documentation

Safety Information

Symbol 
GHS02  GHS02
Signal word 
Warning
Hazard statements 
RIDADR 
UN1224 - class 3 - PG 3 - Ketones, liquid, n.o.s., HI: all
WGK Germany 
3
Flash Point(F) 
125.6 °F
Flash Point(C) 
52 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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