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337331 Aldrich

Dichloro(1,5-cyclooctadiene)ruthenium(II), polymer Green Alternative

95%

Synonym: (1,5-Cyclooctadiene)ruthenium(II) chloride, Ruthenium(II) chloride 1,5-cyclooctadiene complex

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Reproducibility: Validated Products, Ru Catalysts, Ruthenium Catalysts,
assay   95%
greener alternative product characteristics   Catalysis
Learn more about the Principles of Green Chemistry.

Description

Packaging

1 g in glass bottle

Application

Versatile Ru catalyst precursor. Used with IMes to catalyze the dehydrogenative coupling of alcohols and amines to form amide bonds.

Versatile ruthenium catalyst precursor. Used with NHC ligand to catalyze greener amide bond formation by dehydrogenative coupling of amines and alcohols.

Amide Synthesis from Alcohols and Amines by the Extrusion of Dihydrogen

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
1
Protocols & Articles

Articles

Greener Methods: Catalytic Amide Bond Formation

Amide bonds are one of the most frequently utilized disconnections in organic synthesis. Methods to form this vital functionality are commonly superstoichiometric, leading to considerable waste in th...
Keywords: Amidations, Catalysis, Green chemistry, Organic synthesis, Pharmaceutical

Protocols

Bestmann-Ohira Reagent: Synthesis of Alkynes from Aldehydes Protocol

Acetylene chemistry has been and remains an important constituent element of molecular sciences. Its potential and widespread applications extend from organic synthesis through materials science to b...
Keywords: Bestmann-Ohira Reaction, Building blocks, Chromatography, Click chemistry, Eliminations, Evaporation, Materials Science, Metallations, Organic synthesis, Thin layer chromatography

Catalytic Amide Bond Formation: Greener Methods

The amide bond is one of the most important linkages in organic chemistry and constitutes the key functional group in peptides, polymers, and many natural products and pharmaceuticals.  Amides are us...
Keywords: Amidations, Beckmann Rearrangement, Catalysis, Chromatography, Column chromatography, Ligands, Peptide synthesis, Pharmaceutical, Rearrangements, Schmidt Reaction, transformation

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