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337498 Aldrich

(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-iridium(I) hexafluorophosphate

85%

Synonym: (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-Ir(I) PF6, Crabtree’s catalyst, Iridium(I) hexafluorophosphate (1,5-Cyclooctadiene)-(pyridine)-(tricyclohexylphosphine) complex, [Ir(cod)(PCy3)(py)]PF6

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Iridium More...
InChI Key   UJXHUUQZACSUOG-KJWGIZLLSA-N
assay   85%
mp   175 °C (dec.)(lit.)

Description

Application

Catalyst for alkene hydrogenation, isomerization, and hydroboration; also for hydrogen isotope exchange reaction.

Homogeneous hydrogenation catalyst hydroboration catalyst.

Packaging

50, 250 mg in glass bottle

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Robert Crabtree Group – Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Robert Crabtree Group – Professor Product Portal
Keywords: Asymmetric synthesis, Hydrogenations

Peer-Reviewed Papers
15

References

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