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339768 Aldrich

Tetrakis(acetonitrile)palladium(II) tetrafluoroborate

Synonym: NSC 307191, Palladium(II) tetrafluoroborate tetraacetonitrile complex

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts, Palladium
InChI Key   YWMRPVUMBTVUEX-UHFFFAOYSA-N
mp   230 °C (dec.)(lit.)

Description

Packaging

1 g in glass bottle

250 mg in glass bottle

Application

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Reactant involved in:
• Reactions where it plays a role as the metal source due to weakly coordinated acetonitrile ligands

Precursor for:
• Synthesis of dendritic SCS-pincer palladium complexes
• Palladium complexes of click ligands
• Dipalladium catalysts for use in Heck cross-coupling, Suzuki cross-coupling, and aldehyde olefination

General description

Tetrakis(acetonitrile)palladium(II) tetrafluoroborate is a stronger Lewis acid. It participates in the preparation of 2:1 complex [Pd(1,2-bis(2′-pyridylethynyl)benzene)2](BF4]2, by Sonogashira cross-coupling reaction.

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
Protocols & Articles

Articles

Heck Reaction

The Heck reaction is the palladium catalyzed cross-coupling reaction between alkenes, and aryl or vinyl halides (or triflates) to afford substituted alkenes.1,2 It is a useful carbon–carbon bond form...
Keywords: Asymmetric synthesis, Cancer, Catalysis, Coupling reactions, Cross couplings, Heck Reaction, Herbicides, Ligands, Organic synthesis, Solvents

Related Content

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Palladium catalyzed cross-coupling reactions have revolutionized the way in which molecules are constructed. From the fields of organic synthesis and medicinal chemistry, to materials science and pol...
Keywords: Catalysis, Coupling reactions, Cross couplings, Materials Science, Medicinal chemistry, Organic synthesis, Polymer science, Type, transformation

Peer-Reviewed Papers
15

References

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