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341568 Aldrich

Benzeneruthenium(II) chloride dimer

Synonym: (Benzene)dichlororuthenium dimer, Benzeneruthenium dichloride dimer, Bis(benzene)tetrachlorodiruthenium, Bis[(benzene)dichlororuthenium], Dibenzenetetrachlorodiruthenium

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Ru Catalysts, Ruthenium Catalysts
InChI Key   YGXMUPKIEHNBNQ-UHFFFAOYSA-J

Description

Packaging

1, 5 g in glass bottle

Application

Hydrosilylation Catalysts

• Catalyst for SNAr reactions of fluoroarenes and cyclic amines (eq. 1)
• Precatalyst for the hydrogenation of β-keto esters (eq. 2)
• Precursor for the preparation of other ruthenium catalysts (eq. 3)

Price and Availability

Suggested Laboratory Gloves


Laboratory GlovesThis substance has been tested against several types of hand protection for CE compliance. Click below to find the recommended gloves for handling this product.




Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Encapsulated Os Catalysts

Sigma-Aldrich, in collaboration with Reaxa Ltd., is pleased to offer first-to-market catalysts for use in practical synthetic transformations. Reaxa has immobilized osmium tetroxide, a toxic and vola...
Aldrich ChemFiles 2006, 6.5, 6.
Keywords: Dihydroxylations, Immobilization

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Hydrosilylation Catalyst in Chemical Synthesis

Vinylsilanes are versatile organometallic reagents that participate in a variety of reaction paradigms such as Tamao–Fleming oxidation, olefin metathesis, Pd-catalyzed cross-coupling, protodesilylati...
Keywords: Aldol condensation, Asymmetric synthesis, Catalysis, Condensations, Cross couplings, Cyclizations, Cycloadditions, Hydrosilylations, Metathesis, Methods, Olefin metathesis, Oxidations, Reductions, Solvents

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