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343447 Aldrich

5-Isopropyl-1,3-cyclohexanedione

99% (GC)

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Properties

Related Categories Building Blocks, C9, Carbonyl Compounds, Chemical Synthesis, Ketones,
InChI Key   JYJVWRORYGGPHA-UHFFFAOYSA-N
assay   99% (GC)
mp   63-65 °C(lit.)
shipped in   dry ice

Description

Packaging

5 g in poly bottle

Application

5-Isopropyl-1,3-cyclohexanedione may be used as starting reagent for the synthesis of carvotanacetone analogs. It may be used in the preparation of monocyclic terepenes. It may be used in the synthesis of 2H-pyrans, via reaction with α,β-unsaturated aldehydes.

General description

5-Isopropyl-1,3-cyclohexanedione is a cyclic 1,3-diketone. It can be prepared by condensation of isobutylideneacetone with ethyl malonate. 5-Isopropyl-1,3-cyclohexanedione on methylation with methyl iodide yields 5-isopropyl-2-methyl-1,3-cyclohexanedione. A multistep-synthesis of 5-isopropyl-1,3-cyclohexanedione involving aldol condensation, Dieckmann-type annulation, ester hydrolysis and decarboxylation is reported.

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Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles
Peer-Reviewed Papers
15

References

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