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343560 Aldrich

Diisopropyl (ethoxycarbonylmethyl)phosphonate

95%

Synonym: Ethyl (diisopropyl phosphono)acetate

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Properties

Related Categories C-C Bond Formation, Chemical Synthesis, Horner-Wadsworth-Emmons Reagents, Olefination, Synthetic Reagents More...
InChI Key   YZEWJYIDAAGEHA-UHFFFAOYSA-N
assay   95%
refractive index   n20/D 1.427(lit.)
bp   142-143 °C/11 mmHg(lit.)
density   1.06 g/mL at 25 °C(lit.)

Description

Packaging

5 g in glass bottle

Application

Reactant for:
• Preparation of spiroimine ring fragment of spirolides via stereoselective intermolecular Diels-Alder and aza-Wittig cyclization
• Katsuki-Sharpless epoxidation reaction
• Preparation of nine-membered diallylic sulfonamides as chiral building blocks
• Alpha-phosphono lactams for subsequent Wadsworth-Emmons olefination, and Suzuki coupling reactions to yield diverse pyrrolidinone compounds
• Synthesis of galactosylceramide analog that induces Th1-biased responses in human (NKT) cells
• Stereoselective total synthesis of the ionophore antibiotic zincophorin (M144255)

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
235.4 °F
Flash Point(C) 
113 °C
Protocols & Articles
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