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343706 Aldrich

Dichloro(p-cymene)ruthenium(II) dimer Green Alternative

Synonym: (p-Cymene)ruthenium(II) chloride dimer, Benzene, 1-methyl-4-(1-methylethyl)-, ruthenium complex

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Properties

Related Categories 12 Principles Aligned Products, C-H Activation, Catalysis, Catalysis and Inorganic Chemistry, Catalysts,
InChI Key   LAXRNWSASWOFOT-UHFFFAOYSA-J
greener alternative product characteristics   Catalysis
Learn more about the Principles of Green Chemistry.
mp   247.0-250.0 °C (dec.)(lit.)

Description

Packaging

1, 5 g in glass bottle

Application

Hydrosilylation Catalysts

Catalyst for greener amine synthesis by reduction of imines with PMHS or hydrogen-borrowing.

A Practical and Benign Synthesis of Primary Amines through Ruthenium-Catalyzed Reduction of Nitriles

Ruthenium-Catalyzed N-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology

Cyclometalated ruthenium complexes with arylimines and nitrogen-containing heterocycles via C-H bond activation

General description

Sigma Life Science is committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Price and Availability

Suggested Laboratory Gloves


Laboratory GlovesThis substance has been tested against several types of hand protection for CE compliance. Click below to find the recommended gloves for handling this product.




Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
2
Protocols & Articles

Articles

Encapsulated Os Catalysts

Sigma-Aldrich, in collaboration with Reaxa Ltd., is pleased to offer first-to-market catalysts for use in practical synthetic transformations. Reaxa has immobilized osmium tetroxide, a toxic and vola...
Aldrich ChemFiles 2006, 6.5, 6.
Keywords: Dihydroxylations, Immobilization

Related Content

Hydrosilylation Catalyst in Chemical Synthesis

Vinylsilanes are versatile organometallic reagents that participate in a variety of reaction paradigms such as Tamao–Fleming oxidation, olefin metathesis, Pd-catalyzed cross-coupling, protodesilylati...
Keywords: Aldol condensation, Asymmetric synthesis, Catalysis, Condensations, Cross couplings, Cyclizations, Cycloadditions, Hydrosilylations, Metathesis, Methods, Olefin metathesis, Oxidations, Reductions, Solvents

Peer-Reviewed Papers
15

References

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