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343870 Aldrich

1-Bromo-3-(trifluoromethoxy)benzene

99%

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Properties

Related Categories Building Blocks, C2 to C7, Chemical Synthesis, Ethers, Organic Building Blocks,
InChI Key   WVUDHWBCPSXAFN-UHFFFAOYSA-N
assay   99%
refractive index   n20/D 1.462(lit.)
density   1.62 g/mL at 25 °C(lit.)

Description

Packaging

5 g in ampule

Application

1-Bromo-3-(trifluoromethoxy)benzene may be used in the preparation of 1,2-dehydro-3-(trifluoromethoxy)benzene. It may be used in the synthesis of new electronically deficient atropisomeric diphosphine ligand (S)-CF3O-BiPhep [2,2′-bis(diphenylphosphino)-6,6′-ditrifluoromethoxy-1,1′-biphenyl].

General description

1-Bromo-3-(trifluoromethoxy)benzene undergoes Diels-Alder reaction with lithium diisopropylamide (LDA) in THF and furan, to yield the corresponding 1,4-dihydro-1,4-epoxy-5- or 6-(trifluoromethoxy)naphthalenes.

Price and Availability

Safety & Documentation

Safety Information

WGK Germany 
3
Flash Point(F) 
145.4 °F
Flash Point(C) 
63 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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Z693847 Scienceware® Break-Safe ampule opener

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94791 SnapIT Ampule Opener, Regular, for 1-2ml, 5-10ml, 10-15ml ampoules
43917 SnapIT Ampule Opener, large, for 5-10ml, 10-15ml, 20-25ml ampoules

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