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347116 Aldrich

Samarium(II) iodide solution

0.1 M in THF, contains samarium chips as stabilizer

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Properties

Related Categories 25mL Sure/Seal Reagents, Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Materials Science,
InChI Key   UAWABSHMGXMCRK-UHFFFAOYSA-L
form   liquid
contains   samarium chips as stabilizer
concentration   0.1 M in THF
density   0.922 g/mL at 25 °C
storage temp.   2-8°C

Description

Application

A promoter of reactions involving samarium ketyl aryl cyclizations.

An effective single-electron reducing agent for the promotion of ketone-olefin and pinacol coupling reactions under mild conditions. Often both intramolecular and intermolecular couplings proceed in a highly stereoselective fashion. Starting material for the synthesis of new heteroleptic samarium aryloxide/cyclopentadienide complexes.

Packaging

1 L in Sure/Seal™

25, 4×25, 100 mL in Sure/Seal™

The 25 mL Sure/Seal bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Price and Availability


Cross-Coupling Guide

Ultra-High Purity Inorganics
Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Supplemental Hazard Statements 
May form explosive peroxides.
RIDADR 
UN 2056 3 / PGII
WGK Germany 
3
Flash Point(F) 
-2.2 °F
Flash Point(C) 
-19 °C

Documents

Certificate of Analysis

Certificate of Origin

Protocols & Articles

Articles

The Rare Earth Crisis—The Supply/Demand Situation for 2010–2015

K.A. Gschneidner, Jr. Ames Laboratory, U.S. Department of Energy and Department of Materials Science and Engineering Iowa State University, Ames, Iowa 50011-3020, USA Email: cagey@ameslab.gov
Keywords: Absorption, Automotive, Capillary electrophoresis, Catalysis, Ceramics, Coloring agents, Detection methods, Environmental, Industries, Magnetic resonance imaging, Materials Science, Oxidations, Poisons, Reductions, Scintillation, Semiconductor, Separation, Substitutions

Peer-Reviewed Papers
15

References

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