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357758 Aldrich

Methyl thiosalicylate

97%

Synonym: Methyl 2-mercaptobenzoate

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Properties

Related Categories Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfur Compounds, Thiols/Mercaptans More...
InChI Key   BAQGCWNPCFABAY-UHFFFAOYSA-N
assay   97%
refractive index   n20/D 1.591(lit.)
bp   98-100 °C/2 mmHg(lit.)
density   1.223 g/mL at 25 °C(lit.)

Description

Packaging

5, 25 g in glass bottle

Application

Methyl thiosalicylate may be used:
• in the synthesis of thioxanthone, an efficient enantioselective organocatalyst for the intramolecular [2+2] photocycloaddition reaction
• as anionic bidentate ligand, in the preparation of ′2+1′ type complexes of [(99m)Tc]-tricarbonyltechnetium(I) and [(188)Re]-tricarbonylrhenium(I)
• in the synthesis of a series of benzisothiazolone derivatives
• in the synthesis of a new fused benzoheterocyclic compound, [1]benzothieno[3,2-b]furan

General description

Methyl thiosalicylate may be benefecial in preventing mercury-induced toxicity.

Price and Availability

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
RTECS 
DH3500000
Flash Point(F) 
235.4 °F
Flash Point(C) 
113 °C
Protocols & Articles

Articles

Nicewicz Photoredox Catalysts for Anti-Markovnikov Alkene Hydrofunctionalization

While Markovnikov alkene reactivity is very well developed and utilized commonly in the synthesis of commodity and research chemicals, catalytic access to the anti-Markovnikov-selective adducts is a ...
Keywords: Catalysis, Cyclizations, Cycloadditions, Decarboxylations, Hydroaminations, Infrared spectroscopy, Oxidations

Peer-Reviewed Papers
15

References

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