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359408 Aldrich

Methoxycarbonylsulfenyl chloride

97%

Synonym: S-Chloro O-methyl thiocarbonate

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Properties

Related Categories Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfenyl Halides, Sulfur Compounds More...
InChI Key   TXJXPZVVSLAQOQ-UHFFFAOYSA-N
assay   97%
refractive index   n20/D 1.481(lit.)
bp   133-134 °C(lit.)
density   1.399 g/mL at 25 °C(lit.)
storage temp.   2-8°C

Description

Packaging

1, 5 mL in glass bottle

Application

Methoxycarbonylsulfenyl chloride may be used to prepare 3-[(methoxycarbonyl)dithio]-L-alanine, via reaction with L-cysteine. It is suitable for use in the synthesis of 3-2 pyridinyldithio propanoic acid hydrazide (PDPH), an important heterobifunctional crosslinker widely used in bioconjugate techniques for making macromolecule-drug conjugates.

General description

Methoxycarbonylsulfenyl chloride is a sulfenyl carbonyl compound. Photoinduced fragmentations of methoxycarbonylsulfenyl chloride is investigated in the gaseous phase by using synchrotron radiation and multicoincidence techniques. The molecular structure and conformational properties of methoxycarbonylsulfenyl chloride is studied in the gas and solid phases by gas electron diffraction, low-temperature X-ray diffraction and vibrational spectroscopy. The anomeric and mesomeric effects in methoxycarbonylsulfenyl chloride is reported.

Price and Availability

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 2920 3(8) / PGII
WGK Germany 
3
Flash Point(F) 
129.2 °F
Flash Point(C) 
54 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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