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364975 Aldrich

(Triphenylphosphine)copper hydride hexamer

90%

Synonym: Cuprous hydride triphenylphosphine hexamer, Hydrido(triphenylphosphine)copper(I) hexamer, Stryker’s reagent, Triphenylphosphine–Copper(I) hydride Hexamer

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Properties

Related Categories Chemical Synthesis, Metal Hydrides, Reduction, Synthetic Reagents
InChI Key   PYHLOCIDGQNZFY-UHFFFAOYSA-N
assay   90%

Description

Packaging

1, 5 g in glass bottle

Application

Catalyst for:
• Conjugate reduction of ortho-substituted cinnamic esters to form copper enolates
• Chemoselective preparation of alcohols via hydrogenation of aldehydes
• 1,2-addition/transmetalation reactions
• Synthesis of monomer for preparation of phosphorus- and silicon-containing epoxy resins
• Hydrosilylation reactions
• Chiral hydrogenation reactions
• Hydrostannation of activated alkynes

Some useful synthetic applications of (Triphenylphosphine)copperhydride hexamer include stoichiometric and catalytic hydrogenations, chemoselective conjugate reductions, as well as regiospecific and stereoselectiveconjugate hydride reductions.

General description

Triphenylgermanium hydride is a hydrogen donor.

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles
Peer-Reviewed Papers
15

References

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