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366315 Aldrich

Tris(dibenzylideneacetone)dipalladium(0)-chloroform adduct

Synonym: Dipalladium-tris(dibenzylideneacetone)chloroform complex, Pd2(dba)3 · CHCl3

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts, Palladium
InChI Key   LNAMMBFJMYMQTO-FNEBRGMMSA-N
mp   131-135 °C(lit.)

Description

Packaging

1 g in glass bottle

250 mg in glass bottle

Application

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Tris(dibenzylideneacetone)dipalladium(0)-chloroform adduct (Pd2dba3·CHCl3) was used in the following studies:
• To compose the catalytic system for the preparation of homoallylpalladium complexes.These complexes underwent in situ Stille type cross coupling with various vinyltin reagents to afford the cyclized products bearing allyl appendages.
• As palladium source in the asymmetric transformations of 3,4-epoxy-1-butene.
• As catalyst for the Heck cross-coupling reaction of iodobenzene with styrene.
• As cyclization catalyst.
• As catalyst for [2+2+2] cycloaddtion of didehydrotriphenylenes to the corresponding extended triphenylenes.
• As catalyst for the carbonylation of b,b-imidoyl iodides to the corresponding imidate esters used, in turn, to prepare cyclic, quaternary amino acids.

General description

Tris(dibenzylideneacetone)dipalladium(0)-chloroform adduct (Pd2dba3·CHCl3) is reported to serve as effective precatalysts, or precursors to the active Pd(0) catalyst.

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Essence of Chemistry

Cross-Coupling Guide
Safety & Documentation

Safety Information

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Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Catalysts and Metals

Aldrich supplies a large variety of catalysts and metals that are of increasing importance to the synthetic organic chemist. This vast array of products is separated into two major categories: homoge...
ChemFiles Volume 1 Article 3

Heck Reaction

The Heck reaction is the palladium catalyzed cross-coupling reaction between alkenes, and aryl or vinyl halides (or triflates) to afford substituted alkenes.1,2 It is a useful carbon–carbon bond form...
Keywords: Asymmetric synthesis, Cancer, Catalysis, Coupling reactions, Cross couplings, Heck Reaction, Herbicides, Ligands, Organic synthesis, Solvents

Transition-Metal Catalysts

A variety of transition-metal catalysts for the Suzuki coupling reaction are available from Aldrich. The majority of these catalysts are palladium- and nickelbased, typically utilizing phosphine-deri...
ChemFiles Volume 1 Article 1
Keywords: Coupling reactions, Ligands, Suzuki coupling

Related Content

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Palladium catalyzed cross-coupling reactions have revolutionized the way in which molecules are constructed. From the fields of organic synthesis and medicinal chemistry, to materials science and pol...
Keywords: Catalysis, Coupling reactions, Cross couplings, Materials Science, Medicinal chemistry, Organic synthesis, Polymer science, Type, transformation

Peer-Reviewed Papers
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