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366463 Aldrich

Methyl nitroacetate

98%

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Properties

Related Categories Building Blocks, C2 to C5, Carbonyl Compounds, Chemical Synthesis, Esters,
InChI Key   ALBSWLMUHHZLLR-UHFFFAOYSA-N
assay   98%
refractive index   n20/D 1.425(lit.)
bp   195-198 °C(lit.)
density   1.294 g/mL at 25 °C(lit.)

Description

Packaging

1, 5 g in glass bottle

Application

Methyl nitroacetate may be used:
• in the preparation of aromatic and heteroaromatic linear (E)-α-nitro-arylpentenoates
• to generate phenyliodonium ylide, used in the highly enantioselective and diastereoselective Cu(I)-catalyzed cyclopropanation of alkenes
• in the preparation of methyl (Z)-2-nitro-3-(4-nitrophenyl)-2-propenoate, via reaction with 4-nitrobenzylideneaniline

Price and Availability

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
2
RTECS 
AJ1093000
Flash Point(F) 
221 °F
Flash Point(C) 
105 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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