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36815 Aldrich

1-(Diethoxymethyl)imidazole

≥97.0%

  • CAS Number 61278-81-7

  • Empirical Formula (Hill Notation) C8H14N2O2

  • Molecular Weight 170.21

  •  Beilstein Registry Number 908482

  •  MDL number MFCD00956331

  •  PubChem Substance ID 57649666

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Properties

Related Categories Building Blocks, C3 to C8, Chemical Synthesis, Heterocyclic Building Blocks, Imidazoles More...
InChI Key   NNQBAGFIYBBAFL-UHFFFAOYSA-N
assay   ≥97.0%
refractive index   n20/D 1.464
density   1.041 g/mL at 20 °C(lit.)
storage temp.   2-8°C

Description

Packaging

10 mL in glass bottle

Application

1-(Diethoxymethyl)imidazole may be used in the preparation of various hydroxy- and amino-functionalized imidazoles, via isoprene-mediated lithiation followed by reaction with an electrophile.

General description

1-(Diethoxymethyl)imidazole is an orthoamide protected imidazole. The dianion reacts selectively at the 2 position 1-(Diethoxymethyl)imidazole is a 1-substituted imidazoles. Isoprene-mediated lithiation of 1-(diethoxymethyl)imidazole, leads to the preparation of the corresponding 2-lithio intermediate, which reacts with different electrophiles to afford 2-functionalised imidazoles.

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Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
233.6 °F
Flash Point(C) 
112 °C

Documents

Certificate of Analysis

Protocols & Articles
Peer-Reviewed Papers
15

References

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