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371289 Aldrich

2-Bromo-3-methyl-2-butene

96%

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Properties

Related Categories Alkenyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks More...
InChI Key   DBELOSOZLGEZBM-UHFFFAOYSA-N
assay   96%
contains   copper pellets as stabilizer
refractive index   n20/D 1.474(lit.)
bp   40 °C/75 mmHg(lit.)
density   1.284 g/mL at 25 °C(lit.)

Description

Packaging

5, 25 mL in glass bottle

Application

2-Bromo-3-methyl-2-butene may be used in the preparation of:
• 2,3,4,5-tetramethyl-2,4-hexadiene
• 2-iodo-3-methyl-2-butene
• diastereomers of 2-amino-3-hydroxy-4,5-dimethylhexanoic acid
• lithium reagent, 2-lithio-3-methylbut-2-ene
• D-allo-(2R,3R,4R)-2-amino-3-hydroxy-4,5-dimethylhexanoic acid-containing peptide, pipecolidepsin A.

General description

2-Bromo-3-methyl-2-butene is a vinylic bromide compound. Palladium/di-1-adamantyl-n-butylphosphine-catalyzed reductive carbonylation of 2-bromo-3-methyl-2-butene has been reported. Cross-coupling reaction of 2-bromo-3-methyl-2-butene with potassium 6-(benzoyloxy)hexyltrifluoroborate and 3-(benzoyloxy)propyltrifluoroborate has been investigated.

Price and Availability

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 1992 6.1(3) / PGIII
WGK Germany 
3
Flash Point(F) 
77 °F
Flash Point(C) 
25 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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