• USA Home
  • 373621 - 4,4′-Dipyridyl N,N′-dioxide hydrate

EMAIL THIS PAGE TO A FRIEND
373621 Aldrich

4,4′-Dipyridyl N,N′-dioxide hydrate

98%

Purchase

Properties

Related Categories Building Blocks, C10, Chemical Synthesis, Heterocyclic Building Blocks, Pyridines More...
InChI Key   WGMXNNUHJLHXQI-UHFFFAOYSA-N
assay   98%
mp   220 °C (dec.)(lit.)
solubility   water: soluble25 mg/mL, clear, yellow

Description

Application

4,4′-Dipyridyl N,N′-dioxide may be used:
• as bidentate ligand in the preparation of co-ordination polymers of terbium(III)
• as ligand in the preparation of 2D CuII complex, with a stacked wavelike structure, and 3D materials, with CoII and NiII
• in the preparation of a Mg-based luminescent MIL-53 metal-organic framework (MOF)

General description

4,4′-Dipyridyl N,N′-dioxide reacts with various transition-metal salts in MeOH to afford a range of coordination polymers with 1-D chain and 2-D sheet architectures incorporating 36-hxl and 44-sql topologies. 4,4′-Dipyridyl N,N′-dioxide is reported to undergo hydrothermal reaction with d(10) metal ions (Cd2+ and Zn2+) to form three-dimensional grid-like coordination polymers. The electron density of the halogen-bonded complex of 4,4′-dipyridyl-N,N′-dioxide with 1,4-diiodotetrafluorobenzene at 90K has been studied by X-ray diffraction.

Price and Availability

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

Protocols & Articles
Related Products

Technical Service:

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Bulk Ordering & Pricing:

Need larger quantities for your development, manufacturing or research applications?