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374377 Aldrich

2-(Triphenylphosphoranylidene)propionaldehyde

98%

Synonym: 1-Formylethylidenetriphenylphosphorane

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Properties

Related Categories Aldehydes, Building Blocks, C-C Bond Formation, C13-C60, Carbonyl Compounds,
InChI Key   VHUQEFAWBCDBSC-UHFFFAOYSA-N
assay   98%
mp   219-221 °C(lit.)

Description

Packaging

1, 10 g in glass bottle

Application

Reactant for:
• Preparation of acitretin analogs with antitumor activity
• Stereoselective synthesis of essential building blocks of phorboxazole A via hetero Diels-Alder and stereoselective hetero-Michael addition/equilibration
• Preparation of C1-C14 fragment of sarcoglaucol-16-one via Z-selective ando-type Horner-Wadsworth-Emmons olefination
• Wittig reactions
• Synthesis of ring-expanded and epothilone-hybridized macrosphelide analogs as apoptosis-inducing agents
• Preparation of phosphonic acid-containing analogs of mycophenolic acid as inhibitors of IMPDH

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles
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