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374733 Aldrich

2,6-Diisopropylaniline

97%

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Properties

Related Categories Amines, Building Blocks, C12, Chemical Synthesis, Nitrogen Compounds,
vapor pressure   <0.01 mmHg ( 20 °C)
InChI Key   WKBALTUBRZPIPZ-UHFFFAOYSA-N
assay   97%
refractive index   n20/D 1.532(lit.)
bp   257 °C(lit.)
mp   −45 °C(lit.)
density   0.94 g/mL at 25 °C(lit.)

Description

Packaging

5, 25 g in glass bottle

Application

2,6-Diisopropylaniline may be used in the preparation of multitopic Schiff-base ligand precursors. It may be used in the preparation of NSN-donor proligand, 4,5-bis(2,6-diisopropylanilino)-2,7-di-tert-butyl-9,9-dimethylthioxanthene. It may be used to prepare N-heterocyclic carbene complexes for α-arylation of acyclic ketones, amination of haloarenes, and aqueous Suzuki coupling.

2,6-Diisopropylaniline may be used in the preparation of organocatalyst based on naphthalene diimides (NDIs).

General description

2,6-Diisopropylaniline is an amine. It undergoes condensation with triacetylmethane in toluene in the presence of p-toluenesulfonic acid provides 3-[1-(2,6-diisopropylphenylamino)ethylidene]pentane-2,4-dione.

2,6-Diisopropylaniline is an aromatic amine. It reacts with bis(trimethylsilylmethyl)yttrium complexes supported by bulky amidopyridinate (Ap) and amidinate (Amd) ligands to afford yttrium alkyl anilido species. This reaction involves the elimination of TMS (Trimethylsilane).

Price and Availability

Safety & Documentation

Safety Information

Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
2
RTECS 
BX4025000
Flash Point(F) 
242.6 °F
Flash Point(C) 
117 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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