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377945 Aldrich

1-(Triisopropylsilyl)pyrrole

95%

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Properties

Related Categories Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, Pyrroles
InChI Key   FBQURXLBJJNDBX-UHFFFAOYSA-N
assay   95%
refractive index   n20/D 1.492(lit.)
bp   78 °C/0.4 mmHg(lit.)
density   0.904 g/mL at 25 °C(lit.)

Description

Packaging

5, 25 mL in glass bottle

Application

1-(Triisopropylsilyl)pyrrole may be employed as reagent in perfluoroalkylation and Vilsmeier formylation reactions. It may be used in the preparation of:
• ethyl 2-(2,4-dinitrophenylhydrazono]-3-[ 1-(triisopropylsily1)-pyrrol-2-yflpropanoate
• heterocyclic base, 3-nitropyrrole
• 3-nitropyrrole, required for the synthesis of 1 -(2′-deoxy-β-D-ribofuranosyl)-3-nitropyrrole

General description

1-(Triisopropylsilyl)pyrrole (TISP), a heterocyclic building block, is a pyrrole derivative. TISP has been reported to generate pyrrolic cation radicals during cyclovoltammetric studies, via electroreduction. It participates in various electrophilic substitution reactions specifically at β-position, via reaction with various electrophilic reagents (Br+, I+,NO2+,etc).

Price and Availability

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
224.6 °F
Flash Point(C) 
107 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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