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379670 Aldrich

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane

Synonym: Pd(dppf)Cl2 · CH2Cl2, Pd(dppf)Cl2 · DCM, [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (1:1)



Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts, Palladium
mp   275-280 °C


Analysis Note

Catalyst employed in the borylation of aryl halides with Bis(pinacolato)diboron(473294) as well as the coupling of the derived arylboronic esters with aryl halides leading to biaryls.1 Also used in the synthesis of lactams by CO insertion2 and medium-ring aryl ethers by intramolecular coupling of an aryl halide with an alcohol.3


1, 5, 25 g in glass bottle


Application Guide for Palladium Catalyzed Cross-Coupling Reactions

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Safety Information

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Blood, Central nervous system, Liver
Hazard Codes (Europe) 
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WGK Germany 

Protocols & Articles


Catalysts and Metals

Aldrich supplies a large variety of catalysts and metals that are of increasing importance to the synthetic organic chemist. This vast array of products is separated into two major categories: homoge...
ChemFiles Volume 1 Article 3

Transition-Metal Catalysts

A variety of transition-metal catalysts for the Suzuki coupling reaction are available from Aldrich. The majority of these catalysts are palladium- and nickelbased, typically utilizing phosphine-deri...
ChemFiles Volume 1 Article 1
Keywords: Coupling reactions, Ligands, Suzuki coupling

Related Content

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Palladium catalyzed cross-coupling reactions have revolutionized the way in which molecules are constructed. From the fields of organic synthesis and medicinal chemistry, to materials science and pol...
Keywords: Catalysis, Coupling reactions, Cross couplings, Materials Science, Medicinal chemistry, Organic synthesis, Polymer science, Type, transformation

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