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380237 Aldrich

Tebbe reagent solution

0.5 M in toluene

Synonym: Bis(cyclopentadienyl)-μ-chloro­(dimethylaluminum)-μ-methylenetitanium

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Properties

Related Categories 25mL Sure/Seal Reagents, C-C Bond Formation, Chemical Synthesis, Olefination, Organometallic Reagents,
InChI Key   QEJAQNUJXFLWSP-UHFFFAOYSA-M
concentration   0.5 M in toluene
density   0.927 g/mL at 25 °C

Description

Application

A versatile methylenation reagent for the conversion of ketones and aldehydes to olefins, it offers facile reaction with hindered ketones and allows the conversion of esters to vinyl ethers.

Tebbe reagent can be used to olefinate aldehydes.

Used to methylenate a chiral polyhydroxyketone with high diasteroselctivity.

Packaging

25, 4×25, 100 mL in Sure/Seal™

The 25 mL Sure/Seal bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Signal word 
Danger
Hazard statements 
RIDADR 
UN 2924 8(3) / PGII
WGK Germany 
3
Flash Point(F) 
39.2 °F
Flash Point(C) 
4 °C
Protocols & Articles

Articles

Reagents for C–C Bond Formation

Aldrich carries a large variety of electrophiles and nucleophiles that are widely used in C–C bond-forming reactions. This group of products contains many organometallic reagents as well as commonly-...
ChemFiles Volume 1 Article 3
Keywords: Acylations, Alkylations

Peer-Reviewed Papers
15

References

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