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386529 Aldrich

Chlorotrimethylsilane

purified by redistillation, ≥99%

Synonym: TMCS, Trimethylchlorosilane, Trimethylsilyl chloride

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Properties

Related Categories Chemical Reagents, Chemical Synthesis, Development Quantities for Research, Protecting and Derivatizing Reagents, Protection and Derivatization,
vapor density   3.7 (vs air)
vapor pressure   100 mmHg ( 25 °C)
InChI Key   IJOOHPMOJXWVHK-UHFFFAOYSA-N
assay   ≥99%
autoignition temp.   752 °F
purified by   glass distillation
  redistillation
expl. lim.   6.4 %
impurities   <0.1% dichlorodimethylsilane
refractive index   n20/D 1.387(lit.)
bp   57 °C(lit.)
mp   −40 °C(lit.)
density   0.856 g/mL at 25 °C(lit.)

Description

Application

Used in Fisher Glycosylation

Packaging

1, 2 L in Sure/Seal™

25, 100, 4×100 mL in Sure/Seal™

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Supplemental Hazard Statements 
Corrosive to the respiratory tract., Reacts violently with water.
RIDADR 
UN1298 - class 3 - PG 2 - Trimethylchlorosilane
WGK Germany 
1
RTECS 
VV2710000
Flash Point(F) 
-18.4 °F
Flash Point(C) 
-28 °C
Protocols & Articles

Articles

Activating Reagents and Protecting Groups

The use of activating agents and protecting groups in organic synthesis is necessary to prevent unwanted side reactions from occurring when using other common reagents such as oxidizing or reducing a...
Chemfiles Volume 1 Article 3
Keywords: Organic synthesis

Peer-Reviewed Papers
15

References

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