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392766 Aldrich

AD-mix-β

Synonym: AD-mix-beta

Purchase

Description

Components

Mixture contains:
(DHQD)2PHAL (Cat. No. 392731) 0.0016 mole
Potassium carbonate, powder 0.4988 mole
Potassium ferricyanide 0.4988 mole
Potassium osmate dihydrate 0.0007 mole

General description

Contains chiral ligand (DHQD)2PHAL

Packaging

10 g in glass bottle

50, 250 g in poly bottle

Legal Information

Sold under license from Rhodia Pharma Solutions.

Application

Catalyst employed in the Sharpless Asymmetric Dihyroxylation of (E,E)- or (E,Z)-1,3-dienoates. Also used in the preparation of ß-hydroxy-γ-lactones from ß,γ-unsaturated esters.

Reagent for Sharpless Asymmetric Dihydroxylation.

Price and Availability

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Supplemental Hazard Statements 
Contact with acids liberates very toxic gas.
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

Certificate of Origin

Protocols & Articles

Articles

Barry Sharpless Group – Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Barry Sharpless Group – Professor Product Portal
Keywords: Asymmetric synthesis, Building blocks, Chemical reactions, Click chemistry, Oxidations, Solvents, transformation

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Keywords: Catalysis, Dihydroxylations, Immobilization, Ligands, Pharmaceutical, Substitutions

Peer-Reviewed Papers
15

References

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