EMAIL THIS PAGE TO A FRIEND
393606 Aldrich

o-Tolylboronic acid

≥95.0%

Synonym: (2-Tolyl)boronic acid, 2-Methyl-1-phenylboronic acid, 2-Methylbenzeneboronic acid, 2-Methylphenylboronic acid, 2-Tolueneboronic acid, o-Boronotoluene, o-Methylphenylboronic acid, o-Tolueneboronic acid

Purchase

Properties

Related Categories Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids,
InChI Key   NSJVYHOPHZMZPN-UHFFFAOYSA-N
assay   ≥95.0%
mp   162-164 °C(lit.)

Description

Other Notes

Contains varying amounts of anhydride

Packaging

1, 5, 25 g in glass bottle

Application

Reagent used for
• Palladium-catalyzed direct arylation of pyrazoles with phenylboronic acids
• Pd-catalyzed arylation using Suzuki-Miyaura cross-coupling in water
• Ruthenium catalyzed direct arylation reactions
• Ligand-free copper-catalyzed coupling reactions
• Copper-catalyzed cross-coupling reactions of diaryl diselenides
• Phosphine-free Suzuki-Miyaura cross-coupling reactions
• Rhodium-catalyzed asymmetric 1,4-addition reactions

Reagent used in Preparation of
• Chiral monophosphorus ligands in asymmetric Suzuki-Miyaura coupling reaction
• Palladium nanoparticles immobilized by click ionic copolymers as recyclable catalysts for Suzuki-Miyaura cross-coupling reaction in water
• Human farnesyl pyrophosphate synthase inhibitors as antitumor agents for multiple myeloma cells

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Arylboronic Acids

Aldrich is pleased to present its complete selection of arylboronic acids, the building blocks of the Suzuki coupling experiment. Most arylboronic acids readily undergo dehydration reactions to give ...
Aldrich ChemFiles 2001, 1.1, 5.
Keywords: Building blocks, Coupling reactions, Dehydration reaction, Suzuki coupling

Boronic Acids

Most boronic acids readily undergo dehydration reactions to give a cyclic (trimer) anhydride. Our selection of boronic acids may contain varying amounts of this cyclic anhydride. Fortunately, the aci...
Aldrich ChemFiles 2007, 7.7, 3.
Keywords: Chemfiles, Coupling reactions, Dehydration reaction, Suzuki coupling

Peer-Reviewed Papers
15

References

Set your institution to view full text papers.
Related Products

Technical Service:

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Bulk Ordering & Pricing:

Need larger quantities for your development, manufacturing or research applications?