|Related Categories||Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, TADDOLs More...|
|optical activity||[α]20/D +280°, c = 1 in ethyl acetate|
|mp||200 °C (dec.)(lit.)|
1 g in glass bottle
Reagent for the highly enantioselective addition of primary alkyl Grignards to ketones.1
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Apart from numerous examples using TADDOLs in metal-catalyzed asymmetric reactions, Rawal recently reported that TADDOLs could be used as Brønsted acid organocatalysts in highly stereoselective heter...
Aldrich ChemFiles 2007, 7.9, 13.
Keywords: Addition reactions, Aminations, Asymmetric synthesis, Catalysis, Substitutions
The chiral auxiliaries TADDOLs (α,α,α,α-tetraaryl-1,3-dioxolane-4,5- dimethanols) developed by Seebach's group have found numerous applications in asymmetric synthesis ranging from utilization as sto...
Keywords: Addition reactions, Asymmetric synthesis, Catalysis, Chiral auxiliaries, Desymmetrizations, Diels-Alder reaction, Fluorinations, Hydrogenations, Metathesis, Nucleophilic additions, Polymerization reactions, Transesterifications
1. Angew. Chem. Int. Ed. Engl. 31, 84, (1992)
FT-IR 2 (2), 1961:D / Structure Index 1, 206:B:8
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