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395315 Aldrich

Ethyl diazoacetoacetate

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Properties

Related Categories Azo/Diazo Compounds, Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks More...
vapor pressure   0.36 psi ( 20 °C)
InChI Key   JWTPSIXYXYNAOU-UHFFFAOYSA-N
refractive index   n20/D 1.474(lit.)
density   1.131 g/mL at 25 °C(lit.)

Description

Packaging

1 g in glass bottle

Application

Ethyl diazoacetoacetate may be used in the preparation of diazoacetoacetate derivatives, via one-pot process involving initial DBU (1,8-Diazabicyclo[5.4.0]undec-7-ene)-promoted Aldol condensation. It may be used in the preparation of β-keto esters, via reaction with aldehydes in the presence of NbCl5 in dichloromethane.

General description

Ethyl diazoacetoacetate is a diazo compound. It participates in Rh2(OAc)4-catalyzed reactions with arylalkylamines and diarylamines. Reaction of ethyl diazoacetoacetate with N-methyl pyrrole and pyrrole derivatives has been studied.

Price and Availability

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
WGK Germany 
3
Flash Point(F) 
185 °F
Flash Point(C) 
85 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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