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396729 Aldrich

(2S,5S)-2,5-Hexanediol

99%, optical purity ee: 99% (GLC)

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Polyols More...
InChI Key   OHMBHFSEKCCCBW-WDSKDSINSA-N
assay   99%
optical activity   [α]20/D +34.5°, c = 9 in chloroform
optical purity   ee: 99% (GLC)
bp   212-215 °C(lit.)
mp   50-53 °C(lit.)

Description

Application

Used in the synthesis of phospholanes. A building block in the synthesis of trans-2,5-dimethylpyrrolidine. C2 symmetric chiral diol with versatile applications as a chiral auxiliary, building block, and chiral ligand.

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Suggested Laboratory Gloves


Laboratory GlovesThis substance has been tested against several types of hand protection for CE compliance. Click below to find the recommended gloves for handling this product.



Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
215.6 °F
Flash Point(C) 
102 °C
Protocols & Articles

Articles

Chiral Diols - Technical Article

Enantiomerically pure C2-symmetrical alkanediols such as (2S,5S)-, and (2R,5R)-hexanediol are valuable building blocks for the synthesis of chiral ligands such as (2S,5S)-dimethylpyrrolidine or (2S,5...
Aldrich ChemFiles 2005, 5.4, 12.
Keywords: Asymmetric synthesis, Building blocks, Catalysis, Chemfiles, Hydrogenations, Ligands

Peer-Reviewed Papers
15

References

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