|Related Categories||Azidation/Diazo Transfer, Azides, Building Blocks, C-X Bond Formation (Non-Halogen), Chemical Biology,|
5, 25 g in glass bottle
Hydroazidation Catalyst for Facile Preparation of Organoazides
Diazo transfer agent.1,2,3
Reagent for synthesis of:
Non-peptidic NK3 receptor antagonists
A late-stage intermolecular C-H olefination
Intramolecular isomuenchnone cycloaddition approach to antitumor agents
Rhodium-catalyzed carbene cyclization cycloaddition cascade reaction of vinylsulfonates
Suzuki-Miyaura cross coupling reaction
Certificate of Analysis
Certificate of Origin
|Precautionary statements||P261-P305 + P351 + P338|
|Personal Protective Equipment||dust mask type N95 (US), Eyeshields, Gloves|
|Hazard Codes (Europe)||Xi|
|Risk Statements (Europe)||36/37/38|
|Safety Statements (Europe)||26-37/39|
Since the preparation of the first organic azide, phenyl azide, by Peter Griess in 1864 this energy-rich and versatile class of compounds has enjoyed considerable interest. In more recent years, comp...
Aldrich ChemFiles 2008, 8.1, 10.
Keywords: Combinatorial synthesis, Cycloadditions, Hydroazidations, Metathesis, Peptide synthesis
The traditional process of drug discovery based on natural secondary metabolites has often been slow, costly, and labor-intensive. Even with the advent of combinatorial chemistry and high-throughput ...
Keywords: 1,3-Dipolar cycloaddition, Catalysis, Chromatography, Click chemistry, Combinatorial synthesis, Cycloadditions, Drug discovery, Hydroazidations, Ligands, Metabolites, Purification, Solvents
New Hydroazidation Catalyst for Facile Preparation of Organoazides The chemistry of organoazides is exceedingly rich, since the azide functionality reacts with electrophiles, nucleophiles, and dipola...
Keywords: Azide formation, Catalysis, Click chemistry, Cycloadditions, Hydroazidations, Ligands, Reductions, Substitutions, transformation
1. Organic Synth. 70, 93, (1992)
2. Synth. Commun. 17, 1709, (1987)
3. Tetrahedron 49, 5109, (1993)
I. A. Sacui and P. Norris, Tetrahedron Lett. 52, 2670-2672, (2011)
F. Grillet, et al., Tetrahedron 67, 2579-2584, (2011)
B. Shi, et al., Adv. Synth. Catal. 351, 3128-3132, (2009)
Palladium-catalyzed oxidative cross-coupling reaction of arylboronic acids with diazoesters for stereoselective synthesis of (E)-Î±,Î²-diarylacrylates. Y. Tsoi, et al., Org. Lett. 12, 4506-4509, (2010)
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