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405418 Aldrich

2,6-Bis(chloromethyl)pyridine

99%

Synonym: α,α′-Dichloro-2,6-lutidine

  • CAS Number 3099-28-3

  • Empirical Formula (Hill Notation) C7H7Cl2N

  • Molecular Weight 176.04

  •  Beilstein Registry Number 116355

  •  MDL number MFCD00142844

  •  PubChem Substance ID 24865315

  • Popular Documents:  FTIR (PDF)  

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Properties

Related Categories Building Blocks, C7, C7 to C8, Chemical Synthesis, Halogenated Heterocycles,
InChI Key   IWQNFYRJSVJWQA-UHFFFAOYSA-N
assay   99%
mp   73-78 °C(lit.)

Description

Packaging

5 g in glass bottle

Application

2,6-Bis(chloromethyl)pyridine may be used in the following studies:
• Synthesis of a sensitive fluorescent chemosensor for Hg2+, composed of two aminonaphthalimide fluorophores and a receptor of 2,6-bis(aminomethyl)pyridine.
• Preparation of carbene pincer ligands, required for the preparation of palladium pincer carbene complex.
• Synthesis of 2-(di-tert-butylphosphinomethyl)-6-diethylaminomethyl)pyridine, PNN ligand.

General description

2,6-Bis(chloromethyl)pyridine is a heterocyclic building block for the synthesis of a variety of pyridine derivatives. It coordinates with metal ions through N-atom to form complexes. The conformational flexibility of the bromomethyl arms makes it an ideal choice for the generation of macrocycles. 2,6-bis(chloromethyl)pyridine crystals are monoclinic with space group P21/c. Its synthesis has been reported. The FT-IR and FT-Raman spectra of 2,6-bis(chloromethyl)pyridine (BCMP) have been recorded in the regions 4000-400cm-1 and 3500-100cm-1, respectively.

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Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
UN 3335
WGK Germany 
3
Protocols & Articles
Peer-Reviewed Papers
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