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407704 Aldrich

4-Methylmorpholine

purified by redistillation, ≥99.5%

Synonym: NMM

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Properties

Related Categories Building Blocks, C4 to C10, Chemical Synthesis, Heterocyclic Building Blocks, Morpholines/Thiomorpholines More...
vapor density   >1 (vs air)
vapor pressure   18 mmHg ( 20 °C)
InChI Key   SJRJJKPEHAURKC-UHFFFAOYSA-N
assay   ≥99.5%
purified by   glass distillation
  redistillation
refractive index   n20/D 1.435(lit.)
bp   115-116 °C/750 mmHg(lit.)
mp   −66 °C(lit.)
density   0.92 g/mL at 25 °C(lit.)

Description

Packaging

1 L in Sure/Seal™

100 mL in Sure/Seal™

Application

4-Methylmorpholine may be used in the preparation of N-ethyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide.

General description

4-Methylmorpholine is an economical cation useful for the preparation of morpholinium cation-based ionic liquids. The experimental FT-IR and FT-Raman spectra of 4-methylmorpholine has been recorded over the range 4000-400cm-1 and 3500-100cm-1 respectively. It undergoes fluorination with cobalt(III) fluoride to afford highly fluorinated morpholines, which were characterized by mass and NMR spectroscopy.

Price and Availability

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 2535 8(3) / PGII
WGK Germany 
1
RTECS 
QE5775000
Flash Point(F) 
57.2 °F
Flash Point(C) 
14 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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