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410438 Aldrich

Methyl (S)-(−)-3-Boc-2,2-dimethyl-4-oxazolidinecarboxylate

98%

Synonym: Methyl (S)-(−)-3-(tert-butoxycarbonyl)-2,2-dimethyl-4-oxazolidinecarboxylate

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Auxiliaries, Oxazolidinone Derivatives
InChI Key   ZNBUXTFASGDVCL-QMMMGPOBSA-N
assay   98%
optical activity   [α]20/D −55°, c = 1.3 in chloroform
optical purity   ee: 99% (HPLC)
refractive index   n20/D 1.443(lit.)
bp   101-102 °C/2 mmHg(lit.)
density   1.082 g/mL at 25 °C(lit.)

Description

Packaging

5 g in glass bottle

Application

Precursor to a configurationally stable serinal derivative (Garner′s aldehyde) that has been used to make azasugars, sphingolipids, and the amino sugar found in calicheamicin, a potent antitumor agent.

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Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NA 1993 / PGIII
WGK Germany 
3
Flash Point(F) 
199.4 °F
Flash Point(C) 
93 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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