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41470 Aldrich

cis-2,6-Dimethylpiperidine

≥97.0% (GC)

Synonym: 2,6-Lupetidine

  • CAS Number 766-17-6

  • Empirical Formula (Hill Notation) C7H15N

  • Molecular Weight 113.20

  •  MDL number MFCD00066304

  •  PubChem Substance ID 57650059

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Properties

Related Categories Building Blocks, C5 to C7, Chemical Synthesis, Heterocyclic Building Blocks, Piperidines More...
InChI Key   SDGKUVSVPIIUCF-KNVOCYPGSA-N
assay   ≥97.0% (GC)
refractive index   n20/D 1.4394(lit.)
  n20/D 1.440
bp   127-128 °C/768 mmHg(lit.)
density   0.84 g/mL at 25 °C(lit.)

Description

Packaging

100 mL in glass bottle

Application

cis-2,6-Dimethylpiperidine [cis-DMP(H)] may be used for the preparation of four new zincates and one new magnesiate, where [TMEDA = N,N,N´,N´-tetramethylethylenediamine; cis-DMP = cis-2,6-dimethylpiperidide; DIBA(H) = diisobutylamine]:
• (TMEDA)·LiZn(cis-DMP)(t Bu)2
• (TMEDA)·NaZn(cis-DMP)(t Bu)2
• (TMEDA)·NaZn(cis-DMP)2(t Bu)
• (TMEDA)·NaZn(DIBA)2(t Bu)
• (TMEDA)·NaMg(cis-DMP)3

Reagent for elimination reactions

Reactant for corrosion inhibitors for iron in HCl

Catalyst for:
Preparation of aliphatic amines
Ketene forming eliminations
Stereoselective synthesis of triflates

Price and Availability

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 1993BF 3 / PGII
WGK Germany 
3
Flash Point(F) 
53.6 °F
Flash Point(C) 
12 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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