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41566 Aldrich

(2R,5R)-(−)-trans-2,5-Dimethylpyrrolidine

≥97.0% (GC)

  • CAS Number 62617-70-3

  • Empirical Formula (Hill Notation) C6H13N

  • Molecular Weight 99.17

  •  Beilstein Registry Number 4652641

  •  MDL number MFCD01863020

  •  PubChem Substance ID 57650066

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Heterocyclic Building Blocks, Pyrrolidines More...
InChI Key   ZEBFPAXSQXIPNF-PHDIDXHHSA-N
assay   ≥97.0% (GC)
optical activity   [α]20/D −19.0±1.5°, c = 2% in methylene chloride
refractive index   n20/D 1.431
density   0.852 g/mL at 20 °C(lit.)
storage temp.   2-8°C

Description

Other Notes

Important chiral auxiliary with a pseudo C2 axis; diastereoselective alkylation of ketone enamines ; Highly stereoselective addition reactions of the enamine of β-keto esters (vinylogous urethanes) ; Radical reactions of unsaturated amides

Packaging

50, 250 mg in glass bottle

Bottomless glass bottle. Contents are inside inserted fused cone.

Price and Availability

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 3286 8(6.1)(3) / PGII
WGK Germany 
3
Flash Point(F) 
44.6 °F
Flash Point(C) 
7 °C

Documents

Certificate of Analysis

Protocols & Articles

Articles

Chiral Vicinal Diamines for Asymmetric Synthesis

Chiral vicinal diamines are of tremendous interest to the synthetic chemist as they are found in many chiral catalysts and pharmaceuticals. Currently, there is no unified approach to making these chi...
Aldrich ChemFiles 2007, 7.9, 7.
Keywords: Chemfiles, Ligands, Pharmaceutical

Peer-Reviewed Papers
15

References

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