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416665 Aldrich

tert-Butyl hydroperoxide solution

5.0-6.0 M in decane

Synonym: 1,1-Dimethylethyl hydroperoxide, 2-Hydroperoxy-2-methylpropane, TBHP

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Properties

Related Categories Chemical Synthesis, Free Radical Initiators, Materials Science, Organic Peroxides, Oxidizing Agents,
InChI Key   CIHOLLKRGTVIJN-UHFFFAOYSA-N
concentration   5.0-6.0 M in decane
impurities   <4% water
refractive index   n20/D 1.402
density   0.808 g/mL at 25 °C
storage temp.   2-8°C

Description

Packaging

25, 100 mL in poly bottle

Application

tert-Butyl hydroperoxide may be used in:
osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions
catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary
oxidation of dibenzothiophenes

General description

tert-Butyl hydroperoxide is an organic peroxide, used in oxidation processes.

Price and Availability

Safety & Documentation

Safety Information

Signal word 
Danger
Precautionary statements 
RIDADR 
UN 3105A8 8(5.2)
WGK Germany 
3
Flash Point(F) 
109.4 °F
Flash Point(C) 
43 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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08168 Timestrip Plus 8 °C

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