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417556 Aldrich

4-Fluorophenylboronic acid

Synonym: (4-Fluorophenyl)boric acid, (4-Fluorophenyl)dihydroxyborane, (4-Fluorophenyl)dihydroxyboron, (p-Fluorophenyl)boric acid, 4-Fluorobenzeneboronic acid, p-Fluorobenzylboronic acid, p-Fluorophenylboronic acid, NSC 142683

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Properties

Related Categories Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids,
InChI Key   LBUNNMJLXWQQBY-UHFFFAOYSA-N
mp   262-265 °C(lit.)

Description

Other Notes

Contains varying amounts of anhydride

Packaging

1, 5 g in glass bottle

25 g in poly bottle

Application

Reagent used for
• Suzuki coupling using microwave and triton B catalyst
• Pd-catalyzed direct arylation of pyrazoles with phenylboronic acids
• Mizoroki-Heck and Suzuki-Miyaura coupling reactions catalyzed by palladium nanoparticles
• Cu-catalyzed Petasis reactions
• Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence
• Ruthenium catalyzed direct arylation
• Rh-catalyzed asymmetric conjugate additions
• Ligand-free copper-catalyzed coupling of nitro arenes with arylboronic acids
• Regioselective arylation and alkynylation by Suzuki-Miyaura and Sonogashira cross-coupling reactions

Price and Availability


KitAlysis - Increasing Catalysis Productivity

Cross-Coupling Guide
Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Arylboronic Acids

Aldrich is pleased to present its complete selection of arylboronic acids, the building blocks of the Suzuki coupling experiment. Most arylboronic acids readily undergo dehydration reactions to give ...
Aldrich ChemFiles 2001, 1.1, 5.
Keywords: Building blocks, Coupling reactions, Dehydration reaction, Suzuki coupling

Boronic Acids - Aldrich ChemFiles 2007, 7.7, 3.

Most boronic acids readily undergo dehydration reactions to give a cyclic (trimer) anhydride. Our selection of boronic acids may contain varying amounts of this cyclic anhydride. Fortunately, the aci...
Aldrich ChemFiles 2007, 7.7, 3.
Keywords: Chemfiles, Coupling reactions, Dehydration reaction, Suzuki coupling

Peer-Reviewed Papers
15

References

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