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419214 Aldrich

Dimethyl 2,6-dibromoheptanedioate

97%

Synonym: 2,6-Dibromoheptanedioic acid dimethyl ester

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Properties

Related Categories Building Blocks, C8 to C9, Carbonyl Compounds, Chemical Synthesis, Esters,
InChI Key   AWWJYEJSCIDADZ-UHFFFAOYSA-N
assay   97%
refractive index   n20/D 1.501(lit.)
bp   130-140 °C/0.01 mmHg(lit.)
density   1.59 g/mL at 25 °C(lit.)
greener alternative category   Re-engineered

Description

Packaging

10, 50 mL in glass bottle

Application

Dimethyl 2,6-dibromoheptanedioate may be used in the following studies:
• Preparation of difunctional poly(n-butyl acrylate) (pBA) macroinitiator.
• As initiator for the synthesis of dibromo-terminated polystyrene, via atom transfer radical polymerization (ATRP).
• Preparation of polytrithiocarbonate, which serves as Reversible Addition-Fragmentation chain Transfer (RAFT) agent for radical polymerization reactions.

General description

Dimethyl 2,6-dibromoheptanedioate acts as a bifunctional initiator in various polymerization reactions. Its electrochemical cyclization affords high yields of three- to six-membered dimethyl 1,2-cycloalkanedicarboxylates.

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Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
UN 3334
WGK Germany 
3
Flash Point(F) 
235.4 °F
Flash Point(C) 
113 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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