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424110 Aldrich

4-Acetylphenyl trifluoromethanesulfonate

99%

Synonym: 4-Acetylphenyl triflate

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Properties

Related Categories Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Triflates, Sulfur Compounds More...
InChI Key   RUMMIUOXQGFCEP-UHFFFAOYSA-N
assay   99%
refractive index   n20/D 1.47(lit.)
bp   75-76 °C/0.35 mmHg(lit.)
density   1.418 g/mL at 25 °C(lit.)

Description

Packaging

5 mL in glass bottle

Application

4-Acetylphenyl trifluoromethanesulfonate (4-acetylphenyl triflate, p-acetylphenyl triflate) may be used in the synthesis of:
• optically active 1-phenyl-1-(4-acetylphenyl)ethane
• (1S,4S)-ethyl 4-(p-acetylphenyl)cyclopent-2-ene-1-carboxylate
• (1S,4S)-methyl 4-(p-acetylphenyl)cyclopent-2-ene-1-carboxylate
• (1S,4S)-4-(p-acetylphenyl)-1-(hydroxymethyl)cyclopent-2-ene
• (1S,4S)-4-(p-acetylphenyl)-1-(t-butyldimethylsiloxy)cyclopent-2-ene
• (1S,4S)-4-(p-acetylphenyl)-1-(benzyloxymethyl)cyclopent-2-ene

General description

4-Acetylphenyl trifluoromethanesulfonate (4-acetylphenyl triflate) is an aryl triflate. It undergoes palladium-catalyzed cross-coupling reaction with optically active (2-cyclohexenyl)difluorophenylsilane to form corresponding cross-coupled product.

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Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
RIDADR 
UN 2810 6.1 / PGIII
WGK Germany 
3
Flash Point(F) 
>235.4 °F
Flash Point(C) 
>113 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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