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425206 Aldrich

2-(Methylthio)cyclohexanone

98%

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Properties

Related Categories Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfides/Disulfides, Sulfur Compounds More...
InChI Key   QFABNUVNDKOIEH-UHFFFAOYSA-N
assay   98%
refractive index   n20/D 1.508(lit.)
bp   45 °C/10.1 mmHg(lit.)
density   1.069 g/mL at 25 °C(lit.)

Description

Packaging

1 g in glass bottle

Application

2-(Methylthio)cyclohexanone may be used as a ketone substrate for the synthesis of cyclic nitrones, by reacting with aspergillusol A.

General description

2-(Methylthio)cyclohexanone is a 2-substituted cyclohexanone. The proportion of axial and equatorial conformation has been measured in chloroform by the Eliel method. It suggests that the in chloroform steric effect dominates over polar effect in contributing to the conformational preference. The stereoselectivity of the reduction of 2-(methylthio)cyclohexanone using different hydrides has been studied.

Price and Availability

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NA 1993 / PGIII
WGK Germany 
3
Flash Point(F) 
192.2 °F
Flash Point(C) 
89 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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