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425575 Aldrich

2-Naphthyl trifluoromethanesulfonate

97%

Synonym: 2-Naphthyl triflate

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Properties

Related Categories Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Triflates, Sulfur Compounds More...
InChI Key   MDWRQYBWVTXIIJ-UHFFFAOYSA-N
assay   97%
mp   30-32 °C(lit.)

Description

Packaging

2 g in glass bottle

Application

2-Naphthyl trifluoromethanesulfonate (2-naphthyl triflate) may be used as an arylating agent in the arylation of 1-(methoxycarbonyl)-2,5-dihydropyrrole by Heck reaction. It may be used as a substrate for coupling with Reformatsky reagent BrZnCH(CH3)(COOtC4H9) in the presence of “reduced” dichlorobis(1,1-diphenylphosphino)ferrocene catalyst.

General description

2-Naphthyl trifluoromethanesulfonate (2-naphthyl triflate) is an aryl triflate. Its ruthenium-catalyzed conversion to 2-bromonaphthalene has been reported.

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Safety & Documentation

Safety Information

Symbol 
GHS05  GHS05
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 3261 8 / PGII
WGK Germany 
3
Flash Point(F) 
235.4 °F
Flash Point(C) 
113 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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