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427055 Aldrich

N-Boc-pyrrolidine

97%

Synonym: tert-Butyl 1-pyrrolidinecarboxylate

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Properties

Related Categories Building Blocks, C9 to C10, Chemical Synthesis, Heterocyclic Building Blocks, Pyrrolidines More...
InChI Key   LPQZERIRKRYGGM-UHFFFAOYSA-N
assay   97%
refractive index   n20/D 1.449(lit.)
bp   80 °C/0.2 mmHg(lit.)
density   0.977 g/mL at 25 °C(lit.)

Description

Packaging

10 g in glass bottle

Application

N-Boc-pyrrolidine may be used in the synthesis of the following:
• 2-aryl-N-boc-pyrrolidines
• scalemic 2-pyrrolidinylcuprates
• 2-alkenyl-N-Boc-pyrrolidines
• 1-deoxycastanospermine
• methylphenidate analogues
• (+)-elaeokanine A

General description

N-Boc-pyrrolidine is an N-substituted pyrrolidine. It is reported that the reactivity of N-Boc-pyrrolidine towards C-H insertion reaction is 2000 times more than cyclohexane. It undergoes α-arylation in the presence of a palladium catalyst with high enantioselectivity.

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Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NA 1993 / PGIII
WGK Germany 
3
Flash Point(F) 
186.8 °F
Flash Point(C) 
86 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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