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43088 Aldrich

Diphenyliodonium chloride

≥98.0% (AT)

Synonym: DPI, NSC 134275

  • CAS Number 1483-72-3

  • Linear Formula (C6H5)2I+Cl-

  • Molecular Weight 316.57

  •  Beilstein Registry Number 3574977

  •  EC Number 216-049-8

  •  MDL number MFCD00011909

  •  PubChem Substance ID 57650143

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Properties

Related Categories Chemical Synthesis, Hypervalent Iodine, Oxidizing Agents, Synthetic Reagents
InChI Key   RSJLWBUYLGJOBD-UHFFFAOYSA-M
assay   ≥98.0% (AT)
mp   233-235 °C (subl.)(lit.)

Description

Other Notes

Reagent used for electrophilic phenylation, e.g. of malonates and dithiocarboxylates

Packaging

5, 25 g in glass bottle

Application

Reactant for:
• Copper-catalyzed cross coupling reactions of purines and diaryliodonium salts
• Synthesis of acetylenic arylselenides
• Sonogashira coupling reactions for the preparation of aryl alkynes
• C-H functionalization for synthesis of (arylmethylene)oxindoles
• Arylation of anilines
• Studies on the visible-light photosensitive system-dlourescein yellow-bis(di-Ph iodonium)
• Investigating the properties of direct and sensitized photolysis of dispersed photoacid generators

Price and Availability

Suggested Laboratory Gloves


Laboratory GlovesThis substance has been tested against several types of hand protection for CE compliance. Click below to find the recommended gloves for handling this product.




Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
GHS06  GHS06
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 2811 6.1 / PGIII
WGK Germany 
3
RTECS 
NN6651666
Protocols & Articles
Peer-Reviewed Papers
15

References

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