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43088 Aldrich

Diphenyliodonium chloride

≥98.0% (AT)

Synonym: DPI, NSC 134275

  • CAS Number 1483-72-3

  • Linear Formula (C6H5)2I+Cl-

  • Molecular Weight 316.57

  •  Beilstein Registry Number 3574977

  •  EC Number 216-049-8

  •  MDL number MFCD00011909

  •  PubChem Substance ID 57650143

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Properties

Related Categories Chemical Synthesis, Hypervalent Iodine, Oxidizing Agents, Synthetic Reagents
InChI Key   RSJLWBUYLGJOBD-UHFFFAOYSA-M
assay   ≥98.0% (AT)
mp   233-235 °C (subl.)(lit.)

Description

Other Notes

Reagent used for electrophilic phenylation, e.g. of malonates and dithiocarboxylates

Packaging

5, 25 g in glass bottle

Application

Reactant for:
• Copper-catalyzed cross coupling reactions of purines and diaryliodonium salts
• Synthesis of acetylenic arylselenides
• Sonogashira coupling reactions for the preparation of aryl alkynes
• C-H functionalization for synthesis of (arylmethylene)oxindoles
• Arylation of anilines
• Studies on the visible-light photosensitive system-dlourescein yellow-bis(di-Ph iodonium)
• Investigating the properties of direct and sensitized photolysis of dispersed photoacid generators

Price and Availability


Laboratory Gloves

Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
GHS06  GHS06
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 2811 6.1 / PGIII
WGK Germany 
3
RTECS 
NN6651666
Protocols & Articles
Peer-Reviewed Papers
15

References

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