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431737 Aldrich

(R)-(+)-N-Benzyl-α-methylbenzylamine

98%

Synonym: (R)-(+)-N-(1-Phenylethyl)benzylamine, (R)-(+)-N-Benzyl-1-phenylethylamine

  • CAS Number 38235-77-7

  • Linear Formula C6H5CH(CH3)NHCH2C6H5

  • Molecular Weight 211.30

  •  Beilstein Registry Number 3589990

  •  MDL number MFCD00015010

  •  PubChem Substance ID 24867044

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Properties

Related Categories Amines, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks More...
InChI Key   ZYZHMSJNPCYUTB-CYBMUJFWSA-N
assay   98%
optical activity   [α]20/D +38°, neat
optical purity   ee: ≥97% (HPLC)
refractive index   n20/D 1.564(lit.)
bp   171 °C/15 mmHg(lit.)
density   1.01 g/mL at 25 °C(lit.)

Description

Packaging

10 mL in glass bottle

50 mL in poly bottle

Application

(R)-(+)-N-Benzyl-α-methylbenzylamine may be used to prepare:
• tert-Butyl (3S)-3-{benzyl[(1R)-1-phenylethyl]amino}-3-(6-methoxypyridin-3-yl)propanoate, an intermediate for the synthesis of the Merck αvβ3 integrin antagonist.
• A conformationally restricted piperidine-based analog of deoxynegamycin.
• 5- and 6-[2,3]-dihydrobenzofuran β-amino acids, which can act as aspartic acid mimetics.

Chiral amine used for enantioselective deprotonations.

Price and Availability

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
235.4 °F
Flash Point(C) 
113 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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