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440272 Aldrich

Dichlorodimethylsilane

≥99.5%

Synonym: DMDCS, Dimethyldichlorosilane

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Properties

Related Categories Chemical Synthesis, Protecting and Derivatizing Reagents, Protection and Derivatization, Silicon-Based, Synthetic Reagents More...
InChI Key   LIKFHECYJZWXFJ-UHFFFAOYSA-N
assay   ≥99.5%
refractive index   n20/D 1.404(lit.)
bp   70 °C(lit.)
mp   −76 °C(lit.)
density   1.07 g/mL at 25 °C(lit.)
storage temp.   2-8°C

Description

Application

Common reagent for synthesis of optically active ansa-mettallocene polymerization catalysts.

Used to prepare a resin bound siloxane with reactivity towards tertiary alcohols.

Packaging

1 L in Sure/Seal™

100 mL in Sure/Seal™

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Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Supplemental Hazard Statements 
Corrosive to the respiratory tract., Reacts violently with water.
RIDADR 
UN1162 - class 3 - PG 2 - Dimethyldichlorosilane
WGK Germany 
1
RTECS 
VV3150000
Flash Point(F) 
33.8 °F
Flash Point(C) 
1 °C
Protocols & Articles

Articles

Organosilanes for Cross-coupling

Over the past several years, Pd-catalyzed cross-coupling of silicon compounds has rapidly gained acceptance as a suitable alternative to more commonly known methods such as: Stille (Sn), Kumada (Mg),...
Aldrich ChemFiles 2006, 6.5, 7.
Keywords: Aldrichimica Acta, Antifungals, Catalysis, Coupling reactions, Cross couplings, Grignard Reaction, Ligands, Metallations, Methods, Protocols, Silylations, Vinylations

Peer-Reviewed Papers
15

References

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