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458139 Aldrich

Luperox® TBH70X, tert-Butyl hydroperoxide solution

70 wt. % in H2O

Synonym: 1,1-Dimethylethyl hydroperoxide, 2-Hydroperoxy-2-methylpropane, tert-Butyl hydroperoxide solution, TBHP

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Properties

Related Categories Chemical Synthesis, Free Radical Initiators, Materials Science, Organic Peroxides, Oxidizing Agents,
InChI Key   CIHOLLKRGTVIJN-UHFFFAOYSA-N
concentration   70 wt. % in H2O
refractive index   n20/D 1.386
bp   96.2 °C
density   0.93 g/mL at 25 °C
storage temp.   2-8°C

Description

Packaging

1, 4 L in poly bottle

18 L in poly drum

25, 100 mL in poly bottle

Legal Information

Product of Arkema Inc.

Luperox is a registered trademark of Arkema Inc.

Application

Iron-Catalyzed Efficient Synthesis of Amides from Aldehydes and Amine Hydrochloride Salts

Iron-Catalyzed Efficient Synthesis of Amides from Aldehydes and Amine Hydrochloride Salts

Versatile reagent for oxidations.

Price and Availability

Safety & Documentation

Safety Information

Signal word 
Danger
Precautionary statements 
RIDADR 
UN 3109A1 8(5.2) / PGII
WGK Germany 
3
Flash Point(F) 
107.6 °F
Flash Point(C) 
42 °C
Protocols & Articles

Articles

CBHA Ligands

Yamamoto and his group developed a new type of ligands based on the C2-symmetric chiral bishydroxamic acid (CBHA). These bidentate ligands have pendant "arms" that can be substituted with a variety o...
Dr. Daniel Weibel
Chemfiles Volume 10 Article 1
Keywords: Asymmetric synthesis, Building blocks, Chemfiles, Epoxidations, Jacobsen Epoxidation, Ligands, Methods, Oxidations, Protocols, Sharpless Epoxidation, Type

Protocols

Boxed reaction: Baran Trifluoromethylation Reaction

Please consult the Safety Data Sheet for information regarding hazards and safe handling practices.
Keywords: Chromatography, Column chromatography

Late Stage Difluoroethylation - Baran's DFES Reagent

From our library of Protocols, Sigma-Aldrich presents Late Stage Difluoroethylation - Baran's DFES Reagent
Keywords: Chromatography, Column chromatography, Thin layer chromatography

Late Stage Difluoromethylation - Baran's DFMS Reagent

From our library of Protocols, Sigma-Aldrich presents Late Stage Difluoromethylation - Baran's DFMS Reagent
Keywords: Chromatography, Nuclear magnetic resonance spectroscopy, Thin layer chromatography

Trifluoromethylation Kit

Please consult the Safety Data Sheet for information regarding hazards and safe handling practices.
Keywords: Chromatography, Column chromatography, Gas chromatography, High performance liquid chromatography, Thin layer chromatography

Related Content

Medical Materials

Whether you need off-the-shelf chemicals for R&D or customized, fit-for-use raw materials for manufacturing applications, Sigma-Aldrich is your ideal medical materials partner. We offer high-quality,...
Keywords: Organic synthesis, Polymer science, Polymerization reactions, Solvents

Peer-Reviewed Papers
15

References

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