EMAIL THIS PAGE TO A FRIEND

459798 Aldrich

Allyl alcohol

≥98.5%

Synonym: 2-Propen-1-ol

Purchase

Properties

Related Categories Allyl Monomers, Materials Science, Monomers, Polymer Science
vapor density   2 (vs air)
vapor pressure   23.8 mmHg ( 25 °C)
assay   ≥98.5%
autoignition temp.   712 °F
expl. lim.   18 %
refractive index   n20/D 1.412(lit.)
bp   96-98 °C(lit.)
mp   −129 °C(lit.)
density   0.854 g/mL at 25 °C(lit.)

Description

Packaging

170, 375, 750 lb in Kilo-Lab™

725 kg in double-wall stainless steel tank

View returnable container options.

Application

Used to induce a mouse model of liver damage that has been used to study the mechanisms of hepatotoxicity and hepatic stem cell-mediated repair.

Price and Availability

Customers Also Viewed

Allyl acetate

99%

Allyl alcohol

≥99%

Allyl alcohol

≥98.5%

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
RIDADR 
UN 1098 3(6.1)
WGK Germany 
2
RTECS 
BA5075000
Flash Point(F) 
71.6 °F
Flash Point(C) 
22 °C

Protocols & Articles

Peer-Reviewed Papers

References

Set your institution to view full text papers.

Hepatic stem cells: existence and origin. Zhang, Y., et al. World J. Gastroenterol. 9, 201-204, (2003)

Loading...


Experimental model of hepatic fibrosis following repeated periportal necrosis induced by allylalcohol. Jung, S.A., et al. Scand. J. Gastroenterol. 35, 969-975, (2000)

Loading...


Iridium-catalyzed enantioselective allylic vinylation. Hamilton JY, Sarlah D, and Carreira EM J. Am. Chem. Soc. 135(3), 994-7, (2013)

Loading...


Enantioselective allylic thioetherification: the effect of phosphoric acid diester on iridium-catalyzed enantioconvergent transformations. Roggen M and Carreira EM Angew. Chem. Int. Ed. Engl. 51(34), 8652-5, (2012)

Loading...


Rhodium-catalyzed cross-aldol reaction: in situ aldehyde-enolate formation from allyloxyboranes and primary allylic alcohols. Lin L, Yamamoto K, Matsunaga S, et al. Angew. Chem. Int. Ed. Engl. 51(41), 10275-9, (2012)

Loading...


Mechanistic investigation of the palladium-catalyzed synthesis of allylic silanes and boronates from allylic alcohols. Larsson JM and Szabó KJ J. Am. Chem. Soc. 135(1), 443-55, (2013)

Loading...


Enantioselective route to ketones and lactones from exocyclic allylic alcohols via metal and enzyme catalysis. Warner MC, Nagendiran A, Bogár K, et al. Org. Lett. 14(19), 5094-7, (2012)

Loading...


Aspects of allyl alcohol toxicity. Atzori L, Dore M, and Congiu L Drug Metabol. Drug Interact. 7(4), 295-319, (1989)

Loading...


Spectrophotometric determination of drugs with iodine. Karuna T, et al. J. Sci. Ind. Res. 65(10), 808, (2006)

Loading...


The Japanese toxicogenomics project: application of toxicogenomics. Takeki Uehara et al Mol. Nutr. Food. Res. 54, 218-27, (2010)

Loading...


Copper-catalyzed tandem trifluoromethylation/semipinacol rearrangement of allylic alcohols. Chen ZM, Bai W, Wang SH, et al. Angew. Chem. Int. Ed. Engl. 52(37), 9781-5, (2013)

Loading...


Steric parameters in the Ir-catalyzed regio- and diastereoselective isomerization of primary allylic alcohols. Li H and Mazet C Org. Lett. 15(24), 6170-3, (2013)

Loading...


A novel murine model to deplete hepatic stellate cells uncovers their role in amplifying liver damage in mice. Puche JE, Lee YA, Jiao J, et al. Hepatology 57(1), 339-50, (2013)

Loading...


Palladium-catalyzed asymmetric allylic alkylation of 3-aryloxindoles with allylidene dipivalate: a useful enol pivalate product. Trost BM, Masters JT, and Burns AC Angew. Chem. Int. Ed. Engl. 52(8), 2260-4, (2013)

Loading...


Developing structure-activity relationships for the prediction of hepatotoxicity. Nigel Greene et al Chem. Res. Toxicol. 23, 1215-22, (2010)

Loading...


Synthesis of highly substituted tetrahydrofurans by catalytic polar-radical-crossover cycloadditions of alkenes and alkenols. Grandjean JM and Nicewicz DA Angew. Chem. Int. Ed. Engl. 52(14), 3967-71, (2013)

Loading...


Total syntheses of multiple cladiellin natural products by use of a completely general strategy. Clark JS, Berger R, Hayes ST, et al. J. Org. Chem. 78(2), 673-96, (2013)

Loading...


N,O-Nucleosides from ene reactions of nitrosocarbonyl intermediates with the 3-methyl-2-buten-1-ol. Quadrelli P, Mella M, Carosso S, et al. J. Org. Chem. 78(2), 516-26, (2013)

Loading...


Catalytic enantioselective epoxidation of tertiary allylic and homoallylic alcohols. Olivares-Romero JL, Li Z, and Yamamoto H J. Am. Chem. Soc. 135(9), 3411-3, (2013)

Loading...


Rh-catalyzed C-C cleavage of benzyl/allylic alcohols to produce benzyl/allylic amines or other alcohols by nucleophilic addition of intermediate rhodacycles to aldehydes and imines. Zhang XS, Li Y, Li H, et al. Chemistry 18(50), 16214-25, (2012)

Loading...


Geminal bis(silyl) enal: a versatile scaffold for stereoselective synthesizing C3,O1-disilylated allylic alcohols based upon anion relay chemistry. Yan L, Sun X, Li H, et al. Org. Lett. 15(5), 1104-7, (2013)

Loading...


Periportal hepatotoxicity due to allyl alcohol: a myriad of proposed mechanisms. Badr MZ J. Biochem. Toxicol. 6(1), 1-5, (1991)

Loading...


Highly stereoselective C-C bond formation by rhodium-catalyzed tandem ylide formation/[2,3]-sigmatropic rearrangement between donor/acceptor carbenoids and chiral allylic alcohols. Li Z, Parr BT, and Davies HM J. Am. Chem. Soc. 134(26), 10942-6, (2012)

Loading...


Iridium-catalyzed asymmetric hydrogenation of α-substituted α,β-unsaturated acyclic ketones: enantioselective total synthesis of (-)-mesembrine. Zhang QQ, Xie JH, Yang XH, et al. Org. Lett. 14(24), 6158-61, (2012)

Loading...


An efficient and convenient palladium catalyst system for the synthesis of amines from allylic alcohols. Banerjee D, Jagadeesh RV, Junge K, et al. ChemSusChem 5(10), 2039-44, (2012)

Loading...


The regio- and stereospecific intermolecular dehydrative alkoxylation of allylic alcohols catalyzed by a gold(I) N-heterocyclic carbene complex. Mukherjee P and Widenhoefer RA Chemistry 19(10), 3437-44, (2013)

Loading...


A predictive ligand-based Bayesian model for human drug-induced liver injury. Sean Ekins et al Drug Metab. Dispos. 38, 2302-8, (2010)

Loading...


Stereoselective synthesis of conjugated trienols from allylic alcohols and 1-iodo-1,3-dienes. Brandt D, Bellosta V, and Cossy J Org. Lett. 14(21), 5594-7, (2012)

Loading...


Synthesis of (-)-morphine: application of sequential Claisen/Claisen rearrangement of an allylic vicinal diol. Ichiki M, Tanimoto H, Miwa S, et al. Chemistry 19(1), 264-9, (2013)

Loading...


Rhodium-catalyzed allylic substitution with an acyl anion equivalent: stereospecific construction of acyclic quaternary carbon stereogenic centers. Evans PA, Oliver S, and Chae J J. Am. Chem. Soc. 134(47), 19314-7, (2012)

Loading...


An aerobic oxidation/homolytic substitution-cascade for stereoselective methylsulfanyl-cyclization of 4-pentenols. Fries P, Müller MK, and Hartung J Org. Biomol. Chem. 11(16), 2630-7, (2013)

Loading...


Total syntheses of pamamycin 607 and methyl nonactate: stereoselective cyclisation of homoallylic alcohols that had been prepared with remote stereocontrol using allylstannanes. Germay O, Kumar N, Moore CG, et al. Org. Biomol. Chem. 10(48), 9709-33, (2012)

Loading...


Directed hydrogenation of acyclic homoallylic alcohols: enantioselective syntheses of (+)- and (-)-laurenditerpenol. Chittiboyina AG, Peddikotla P, Avery MA, et al. J. Org. Chem. 78(18), 9223-32, (2013)

Loading...


[2,3]-Sigmatropic rearrangements of 2-phosphineborane 2-propen-1-ols: rapid access to enantioenriched diphosphine monoxide derivatives. Busacca CA, Qu B, Farber E, et al. Org. Lett. 15(5), 1136-9, (2013)

Loading...


The palladium-catalyzed anti-Markovnikov hydroalkylation of allylic alcohol derivatives. DeLuca RJ and Sigman MS Org. Lett. 15(1), 92-5, (2013)

Loading...


B-(3,3-difluoroallyl)diisopinocampheylborane for the enantioselective fluoroallylboration of aldehydes. Ramachandran PV, Tafelska-Kaczmarek A, and Chatterjee A J. Org. Chem. 77(20), 9329-33, (2012)

Loading...


Validity of inorganic nanosheets as an efficient planar substituent to enhance the enantioselectivity of transition-metal-catalyzed asymmetric synthesis. Zhao LW, Shi HM, An Z, et al. Chemistry 19(37), 12350-5, (2013)

Loading...


Steric analysis of epoxyalcohol and trihydroxy derivatives of 9-hydroperoxy-linoleic acid from hematin and enzymatic synthesis. Thomas CP, Boeglin WE, Garcia-Diaz Y, et al. Chem. Phys. Lipids 167-168, 21-32, (2013)

Loading...


Bradykinetic alcohol dehydrogenases make yeast fitter for growth in the presence of allyl alcohol. Plapp BV, Lee AT, Khanna A, et al. Chem. Biol. Interact. 202(1-3), 104-10, (2013)

Loading...


A new entry to the construction of a quaternary carbon center having a fluorine atom--S(N)2' reaction of γ-fluoroallylic alcohol derivatives with various cyanocuprates. Konno T, Ikemoto A, and Ishihara T Org. Biomol. Chem. 10(40), 8154-63, (2012)

Loading...


Convergent synthesis of conjugated 1,2-disubstituted E-allylic alcohols from two aldehydes and methylenetriphenylphosphorane. Hodgson DM and Persaud RS Org. Biomol. Chem. 10(39), 7949-51, (2012)

Loading...


Synthesis of new sugar derivatives from Stachys sieboldi Miq and antibacterial evaluation against Mycobacterium tuberculosis, Mycobacterium avium, and Staphylococcus aureus. Taku Chiba et al Bioorg. Med. Chem. Lett. 17, 2487-91, (2007)

Loading...


Merck 14,286

Beil. 1,IV,2079

Aldrich MSDS 1, 40:D / Corp MSDS 1 (1), 95:D / FT-IR 1 (1), 138:B / FT-NMR 1 (1), 207:B / IR-Spectra (3), 84:D / RegBook 1 (1), 147:A / Sax 6, 159 / Structure Index 1, 17:D:9 / Vapor Phase 3, 200:C

Related Products

Technical Service:

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Bulk Ordering & Pricing:

Need larger quantities for your development, manufacturing or research applications?