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469068 Aldrich

1-Bromobenzocyclobutene

95%

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Properties

Related Categories Alkenyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks More...
InChI Key   AYNXHFRDABNHRX-UHFFFAOYSA-N
assay   95%
refractive index   n20/D 1.59(lit.)
bp   90 °C/10.5 mmHg(lit.)
density   1.45 g/mL at 25 °C(lit.)

Description

Packaging

1 g in glass bottle

Application

1-Bromobenzocyclobutene may be used in the synthesis of following compounds:
• five-membered zirconacycles
• benzocyclobutenol and benzocyclobutenone
• 2,3-dimethoxyprotoberberinium bromide, via reaction with 3,4-dihydro-6,7-dimethoxyisoquinoline

General description

1-Bromobenzocyclobutene is a useful synthon. It has important applications in organometallic methodology. Reaction between cycloheptatriene, bromoform, potassium carbonate and 18-crown-6 at 140°C yields 1-bromobenzocyclobutene.

Price and Availability

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
204.8 °F
Flash Point(C) 
96 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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