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470449 Aldrich

Tetrakis[1-[[4-alkyl(C11-C13)phenyl]sulfonyl]-(2S)-pyrrolidinecarboxylate]dirhodium(II)

Synonym: Rh2(S-DOSP)4

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Properties

Related Categories Asymmetric Synthesis, Aziridination/Cyclopropanation, C-H Activation, Catalysis and Inorganic Chemistry, Catalysts,
optical activity   [α]20/D −165°, c = 1 in chloroform
mp   195-200 °C(lit.)
storage temp.   2-8°C

Description

Application

Catalyst for asymmetric cyclopropanations.

Catalyst involved in:
• Stereoselective reactions of aryl- and styryldiazoacetates
• Enantioselective C-H carbene insertions
• Asymmetric cyclopropenation of aryl alkynes
• Intermolecular C-H olefination

Packaging

100 mg in poly bottle

Price and Availability

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles
Peer-Reviewed Papers
15

References

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